Apologies for not posting earlier but work gets in the way of the life I want.
It is a Surecal calorifier and the hot water comes up from the centre to the mixer at the back. Below is a view onto the top of the mixer and the outlet at the top goes to the taps and has the pressurised tank tee'd into it. It's the same as Alan's picture only on a vertical cylinder and, from memory, all of that was on the calorifier when we bought it a few years ago.
The water system was working fine but, when we came to use it a couple of weeks ago, we had no hot water. Even the other half will contest that I haven't been 'messing' with the plumbing.